Showing posts with label Inorganic Chemistry. Show all posts
Showing posts with label Inorganic Chemistry. Show all posts

Daily Science Journal (Feb. 7, 2008) — Theoretical physicists at the University of Chicago are suggesting how thin spouts of magma in the Earth's mantle can persist long enough to form hotspot volcanism of the type that might have created the Hawaiian Islands.

University of Chicago physicists Wendy Zhang (left) and Laura Schmidt explain a feature of convecting fluids that colleagues have observed in laboratory experiments. The feature may help explain how hotspot volcanism created the Hawaiian Islands and other such landforms. (Credit: Dan Dry)

Their calculations also apply to tendrils only a few inches long that form in convecting fluids under laboratory conditions. University of Chicago graduate student Laura Schmidt and Wendy Zhang, an Assistant Professor in Physics, will detail their findings in the Feb. 1 issue of the journal Physical Review Letters.


The work was inspired by laboratory experiments conducted by Anne Davaille in France that mimic, in a simplified way, convecting bubbles of magma as they might look deep beneath the Earth's surface. "This is one robust feature of thermal convection," Zhang said.

"It's a useful thing to know because it's the kind of thing that happens in all sorts of different industries, in all sorts of different contexts." These include oil extraction, the chemical industry and in certain biotechnological applications.

Earth scientists also have theorized that mantle plumes form on a regional scale in the Earth's interior, sometimes breaking the surface to form small landmasses, including Hawaii and Iceland. Nevertheless, debate swirls around how, or even if, mantle plumes can account for such surface features.

Geophysicists often liken a pot of boiling water as a smaller, more rapid version of the convection that takes place in the mantle, the layer of Earth that lies between the surface crust and its core. But unlike a pot of water, the Earth's interior consists of layers with different properties.

In laboratory experiments, Anne Davaille, a geophysicist at the University of Paris 7, studies convection in a small tank by heating two layers of colored liquids of differing densities. She observed the formation and persistence of thin tendrils between the layers, which correspond to subsurface plumes measuring scores of miles across.

"It seems so thin and tenuous, how could it possibly manage to hold itself in place over time as everything else is going on around it?" Zhang asked. "Somehow, they manage to hold themselves together."

The tendrils persist for hours, even as experimental conditions change. "These tendrils have fluid flowing through them, and it starts to mix the two layers," Schmidt said. "When the two layers mix, then the viscosity of the layers changes as well."

Following a series of visits to Davaille's lab, Schmidt and Zhang sought to mathematically explain the phenomenon.

"When you look at the shape of these very thin tendrils, there's something very striking that Anne noticed right away," Zhang said. The tendrils seem to emerge from flow lines that resemble the flared-out end of a trumpet. This trumpet shape marked the location of a stagnation point. Both Davaille's experiments and Schmidt's calculations agree: The thinnest tendrils that persist have a stagnation point.

Schmidt had seen a similar stagnation point in experiments she conducted in the laboratory of Sidney Nagel, the Stein-Freiler Distinguished Service Professor in Physics at the University of Chicago. Those experiments involved unmixable fluids, such as water and oil, instead of the fresh water and salt water mixing in Davaille's laboratory.

Nevertheless, the experimental similarities provided Schmidt and Zhang insights that helped solve the problem. In previous studies, other theoreticians suggested how large flows might rise through the tendrils from the base of the hot spots, Schmidt said. She and Zhang approached the problem differently.

"We include the effect of the stagnation point," Schmidt explained. "Our tendrils are really a thin skin or thin layer of the surface between the fluids that is drawn up. It's not a bulk flow going up through the tendril."

Adapted from materials provided by University of Chicago, via EurekAlert!, a service of AAAS.



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Daily Science Journal (Feb. 2, 2008) — Using a tabletop laser, University of Rochester optical scientists have turned pure aluminum, gold. And blue. And gray. And many other colors. And it works for every metal tested, including platinum, titanium, tungsten, silver, and gold.

Gold Aluminum, Blue Titanium, Gold Platinum. (Credit: Richard Baker, University of Rochester)

Chunlei Guo, the researcher who a year ago used intense laser light to alter the properties of a variety of metals to render them pitch black, has pushed the same process further in a paper in today's Applied Physics Letters. He now believes it's possible to alter the properties of any metal to turn it any color—even multi-colored iridescence like a butterfly's wings.

Since the process changes the intrinsic surface properties of the metal itself and is not just a coating, the color won't fade or peel, says Guo, associate professor of optics at the Institute of Optics at the University of Rochester. He suggests the possibilities are endless—a cycle factory using a single laser to produce bicycles of different colors; etching a full-color photograph of a family into the refrigerator door; or proposing with a gold engagement ring that matches your fiancée's blue eyes.


"Since the discovery of the black metal we've been determined to get full control on getting metals to reflect only a certain color and absorb the rest, and now we finally can make a metal reflect almost any color we wish," says Guo. "When we first found the process that produced a gold color, we couldn't believe it. We worked in the lab until midnight trying to figure out what other colors we could make."

Guo and his assistant, Anatoliy Vorobeyv, use an incredibly brief but incredibly intense laser burst that changes the surface of a metal, forming nanoscale and microscale structures that selectively reflect a certain color to give the appearance of a specific color or combinations of colors.

The metal-coloring research follows up on Guo's breakthrough "black metal" discovery in late 2006, when his research team was able to create nanostructures on metal surfaces that absorbed virtually all light, making something as simple as regular aluminum into one of the darkest materials ever created.

Guo's black metal, with its very high absorption properties, is ideal for any application where capturing light is desirable. The potential applications range from making better solar energy collectors, to more advanced stealth technology, he says. The ultra-brief/ultra-intense light Guo uses is produced by a femtosecond laser, which produces pulses lasting only a few quadrillionths of a second. A femtosecond is to a second what a second is to about 32 million years. During its brief burst, Guo's laser unleashes as much power as the entire electric grid of North America does, all focused onto a spot the size of a needlepoint.

The intense blast forces the surface of the metal to form nanostructures—pits, globules, and strands that response incoming light in different ways depending on the way the laser pulse sculpted the structures. Since the structures are smaller than the wavelength of light, the way they reflect light is highly dependent upon their specific size and shape, says Guo. Varying the laser intensity, pulse length, and number of pulses, allows Guo to control the configuration of the nanostructures, and hence control what color the metal reflects.

Guo and Vorobyev also achieve the iridescent coloring by creating microscale lines covered with nanostructures. The lines, arranged in regular rows, cause reflected light of different wavelengths to interfere differently in different directions. The result is a piece of metal that can appear solid purple from one direction, and gray from another, or multiple colors all at once.

To alter an area of metal the size of a dime currently takes 30 minutes or more, but the researchers are working on refining the technique. Fortunately, despite the incredible intensity involved, the femtosecond laser can be powered by a simple wall outlet, meaning that when the process is refined, implementing it should be relatively simple.

The new process has worked on every metal Guo has tried, and the results are so consistent that he believes it will work for every metal known. His team is currently working to find the right tuning to create the rest of the rainbow for the solid-colored metal, including red and green.

Adapted from materials provided by University of Rochester.



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Daily Science Journal (Jul. 16, 2007) — A new study finds that diamonds probably don't crystallize in the atmospheres of planets such as Uranus and Neptune. The conclusion is contrary to recent speculation that small diamonds would spontaneously form in carbon rich layers of the gas giant planets. White dwarf stars, according to the study, are veritable diamond factories.

A simulated snapshot of crystallizing carbon atoms under Uranus-like conditions. (Credit: L. M. Ghiringhelli, C. Valeriani, E. J. Meijer and D. Frenkel, Physical Review Letters)


Physicists at the Universtiet van Amsterdam and the FOM Institute for Atomic and Molecular Physics in the Netherlands performed a numerical analysis showing that at the temperatures and pressures in gas giant planets like Uranus, arrangements of carbon atoms would be much more suitable for creating tiny bits of graphite rather than diamond.

In white dwarfs, on the other hand, the simulation shows that the conditions would cause the carbon atoms to line up in configurations that are much more amenable for diamond crystallization. The conclusion is consistent with the 2004 discovery of a cooling white dwarf star that appears to have a solid diamond core 4000 kilometers across.

Although diamond formation in the atmospheres of gas giants is not strictly impossible, the Dutch physicists say that the odds are exceedingly slim that a diamond could have formed under the conditions that exist in Uranus in the entire lifetime of the universe.

Adapted from materials provided by American Physical Society, via EurekAlert!, a service of AAAS.



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