Nanosieves Save Energy In Biofuel Production

Daily Science Journal (Feb. 13, 2008) — A new type of membrane, developed by scientists of the University of Twente in The Netherlands, can stand high temperatures for a long period of time. This ‘molecular sieve’ is capable of removing water out of e.g. solvents and biofuels. It is a very energy efficient alternative to existing techniques like distillation.

The cylinder is the carrier of a hybrid membrane: a layer of about 100 nanometer thickness. The insert shows a close-up of the layer showing the organic links and pores. From the left of the tube, only water molecules leave the sieve. (Credit: Image courtesy of University of Twente)

Even after testing during 18 months, the new membranes prove to be highly effective, while having continuously been exposed to a temperature of 150 ºC. Existing ceramic and polymer membranes will last considerably shorter periods of time, when exposed to the combination of water and high temperatures. The scientists managed to do this using a new ‘hybrid’ type of material combining the best of both worlds of polymer and ceramic membranes. The result is a membrane with pores sufficiently small to let only the smallest molecules pass through.

Ceramic membranes, made of silica, degrade because they react with water and steam. In the new membrane, part of the ceramic links is therefore replaced by organic links. By doing this, water doesn’t have the chance to ‘attack’ the membranes. Manufacturing the new hybrid membranes is simpler than that of ceramic membranes, because the material is flexible and will not show cracks. What they have in common with ceramic membranes is the rapid flow: an advantage of this is that the membrane surface can be kept small.

The hybrid membranes are suitable for ‘drying’ solvents and biofuels, an application for which there is a large potential market worldwide. The main advantage of membrane technology is that it consumes far less energy than common distillation techniques.

The scientists also foresee opportunities in separating hydrogen gas from gas mixtures. This implies a broad range of applications in sustainable energy. Apart from that, the hybrid membranes are suitable for desalinating water. Using a hybrid membrane that is much smaller than the current polymer membranes, the same result can be achieved.

The results have been achieved in a close cooperation of scientists from the Inorganic Materials Science Group of the MESA+ Institute for Nanotechnology (UT), the Energy Efficiency in Industry department of ECN and the University of Amsterdam. The invention has been patented worldwide.

The article ‘Hybrid ceramic nanosieves: stabilizing nanopores with organic links’ by Hessel Castricum, Ashima Sah, Robert Kreiter, Dave Blank, Jaap Vente and André ten Elshof has been published in Chemical Communications (ChemComm) of the Royal Society of Chemistry in de UK.

Adapted from materials provided by University of Twente.

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History Of Quaternary Volcanism And Lava Dams In Western Grand Canyon

Daily Science Journal (Feb. 11, 2008) — John Wesley Powell wrote in 1895: “...what a conflict of water and fire there must have been [in western Grand Canyon]! Just imagine a river of molten rock running down over a river of melted snow.”

Toroweap Point in Grand Canyon national park. (Credit: iStockphoto/Natalia Bratslavsky)

Over 110 years later, a synthesis of new and existing dates on these lava flows shows that many are significantly younger than initially thought and all are less than 725 thousand years old. The geochronology data indicates four major episodes when lava flows either erupted into the canyon or flowed over the rim into it: 725-475 thousand years ago (ka), 400-275 ka, 225-150 ka, and 150-75 ka.

These flows formed lava dams in western Grand Canyon that had dramatic impact on the Colorado River.

This paper* presents light detection and ranging (lidar) data to establish the elevations of the tops and bottoms of basalt flow remnants along the river corridor. These data show the original extent of now-dissected intra-canyon flows and aid in correlation of flow remnants.

From 725 to 475 ka, volcanism built a high edifice within Grand Canyon in the area of the Toroweap fault, with dike-cored cinder cones on both rims and within the canyon itself. These large-volume eruptions helped drive the far-traveled basalt flows which flowed down-canyon over 120 km. A second episode of volcanism, from 400 to 275 ka, built a 215-m-high dam along the Hurricane fault, about 15 km downstream.

The ca. 200 and 100 ka flows (previously mapped as Gray Ledge) were smaller flows and lava cascades that entered the canyon from the north rim between the Toroweap and Hurricane faults.

The combined results suggest a new model for the spatial and temporal distribution of volcanism in Grand Canyon in which composite lava dams and edifices were generally leaky in proximal areas.

Available data suggest that the demise of volcanic edifices may have involved either large outburst-flood events or normal fluvial deposition at times when the river was established on top of basalt flows. These data highlight complex interactions of volcanism and fluvial processes in this classic locality.

This research, authored by Ryan Crow (University of New Mexico) et al. was published in the February issue of Geosphere, published by the Geological Society of America.

Adapted from materials provided by Geological Society of America.

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